fig2

Confinement of Cu(I) single-atom site with asymmetric coordination modulation in defective metal-organic frameworks for photocatalysis

Figure 2. (A) Product yields of CH3OH, CH3CH2OH, and CH4 over Cu-DOTA@D-MIL during the photocatalytic CO2 reduction process; (B) Stability cycling tests over Cu-DOTA@D-MIL; (C) Product yields over Cu-DOTA@D-MIL, DOTA@D-MIL, D-MIL, MIL-125-NH2, and Cu-DOTA. This figure is adapted with permission from Ref.[15]. Copyright 2026 American Chemical Society. DOTA: N-heteromacrocyclic ligand tetraxetan; D-MIL: defective MIL-125-NH2.

Chemical Synthesis
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